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Pepé Le Pew is a Looney Tunes star and now teaches at Acme Loo. He is the mentor and favorite teacher of Fifi La Fume. On the Looney Tunes shorts, he is seen chasing Penelope Pussycat, because he thinks she is a female skunk.

Appearances on Tiny Toon Adventures

Pepé is voiced by the late Greg Burson on Tiny Toon Adventures.

Pepé makes a debut in the The Looney Beginning episode as a mentor at Acme Looniversity.

Pepé appears in the Season 1 episode, Who Bopped Bugs Bunny?, as the host for Bugs Bunny's awards ceremony in Paris. He welcomes both the Looney and Tiny Toons, who all partake in the audience for the award ceremony. Later in the episode, he is the reporter for France's news network, as Daffy Duck has been framed for the crime of knocking Bugs out and stealing his prized 1958 Shloskar award. He is also the narrator for The Sappy Stanley Story, a short film about the rise and fall of Sappy Stanley.

In Fields of Honey, Pepé is briefly shown at a meeting held by Babs at Acme Looniversity with a majority of the other Looney Tunes teaching staff. Babs is so intent and overzealous on them building a "really big theater" and show nothing but Honey cartoons so that people would come and watch because the "strange voice" (revealed later as Bosko) told her to do so, that she appears to be going mad (even drooling over the table). They promptly send her to the nurse's office to see Elmyra, who also concludes that she is had gone crazy.

Although he does not appear in the Viewer Mail Day episode segment, Out of Odor, it is revealed that Fifi La Fume has a crush on him. Elmyra disguises herself as Pepé in a successful attempt to lure out Fifi and drench her in tomato juice to remove her scent so that she could make the purple skunk her pet "kitty."

In Two-Tone Town, Pepé performs on double bass in an orchestra conducted by Daffy and consisting of other Looney Tunes. Pepé as well as the others in the orchestra are wearing light blue tuxedos and about to perform in front of a full crowd. Buster (in Robin Hood attire and intentions to steal the musical symbols) interrupts the orchestra, but a slightly annoyed Daffy denies his interruption and commands them to perform anyways. Giant musical symbols appear above the orchestra as they play, and Buster begins stealing the symbols, infuriating Daffy further. The angered duck battles Buster atop the symbols, as Pepé and the others continue to play. Daffy loses the battle when he falls and Taz smashes in his head with his cymbals. Buster conducts a final note as Pepé and the rest of the orchestra perform for him.

Pepé appears one more time in the series finale, It's A Wonderful Tiny Toons Christmas Special, when Babs watches a short of his on a projector screen. Here, he is alone with Penelope at a New Year's party and tries to kiss her, but she escapes from his clutches and runs off.

His silhouette appeared in the Tiny Toons Looniversity show on the wall of Looney Tunes.

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